Product ID:PGR, FORMULATED AEROSOL PAINT & GRAFFITI REMOVER
MSDS Date:01/01/1996
FSC:8010
NIIN:00N010570
MSDS Number: CFNNF

STATE CHEMICAL MFG CO

3100 HAMILTON BLVD
CLEVELAND, OH 44114
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

PROPANE, 2-METHYL-; (ISOBUTANE) (MFR'S CAS # 375-28-5)

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: <20%

OSHA PEL N/K

ACGIH TLV: N/K

BUTANE; (N-BUTANE)

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: <20%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

OF COOL WATER FOR AT LEAST 15 MIN. CONTACT

RTECS: 9999999ZZ

WITH THIS PRODUCT.

RTECS: 9999999ZZ

A WINDY DAY WHEN OVERSPRAY CAN BLOW BACK

RTECS: 9999999ZZ

OR TEMPS EXCEEDING 120F. DO NOT STORE NEAR SPARKS OR

RTECS: 9999999ZZ

OR INCINERATE CANS. USE THIS PRODUCT OUTDOORS IF

RTECS: 9999999ZZ

& DOORS OR USE OTHER MEANS TO INSURE FRESH AIR

RTECS: 9999999ZZ

A NIOSH APPRVD RESP MAY OFFER ADDNL PROTECTION. A

RTECS: 9999999ZZ

DO NOT USE IN BASEMENT OR OTHER UNVENTD AREAS.

RTECS: 9999999ZZ

EVAPORATE, THEN DISPOSE OF IN METAL CONTAINERS.

RTECS: 9999999ZZ

PREVENT CLOGGING, TURN CAN UPSIDE DOWN & SPRAY

RTECS: 9999999ZZ

LABEL DIRECTIONS & PRECS BEFORE USING PROD. THESE

RTECS: 9999999ZZ

ONLY. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF

RTECS: 9999999ZZ

METHANE, DICHLORO-; (METHYLENE CHLORIDE (DICHLOROMETHANE))

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: >60%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANOL (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <10%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM; 250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: <20%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A
SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE- SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . MAY BE FATAL OR
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLRORIDE: IARC MONOGRAPHS,
SUPP, VOL 7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ: BLINDNESS IF SWALLOWED. CONTAINS
METHANOL. VAPOR HARMFUL. CONTAINS METHYLENE CHLORIDE. OVEREXPOSURE
TO VAPORS MAY RSLT IN HDCH, NAUS, DROW, DIZZ, NASAL & RESP IRRIT.
DELIBERATE INHAL OF CONT ENTS CAN BE HARMFUL/FATAL. EYE IRRITANT.
DIRECT CONTACT W/SKIN WILL RSLT IN IRRIT. CHRONIC: CAN CAUSE MENTAL
(SUPDAT)
Medical Cond Aggravated by Exposure:HEART DISEASE, RESPIRATORY
DISORDERS.

First Aid:INGEST: DILUTE BY DRINKING SEVERAL GLASSES OF WATER. INDUCE
VOMIT. CALL MD IMMED. INHAL: REMOVE TO FRESH AIR. IF DIFFICULTY IN
BREATHING OR OTHER SYMPS PERSIST, CONTACT MD. NOTE TO MD: OVEREXP
TO METH YLENE CHLORIDE MAY PRDCE ELEVATED CARBOXYHEMOGLOBIN LEVELS.
MAY INCREASE MYOCARDIAL IRRITABILITY. AVOID EPINEPHRINE OR SIMILAR
ACTING DRUGS IF AT ALL POSSIBLE. EYES: FLUSH EYES IMMED W/PLENTY
(ING 6)

Flash Point Method:TOC
Flash Point:-142F,-97C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . WATER MAY BE INEFTIVE BUT MAY BE USED TO KEEP CANS
COOL. USE SHIELDING TO PROTECT PERS (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE . FLAMMABLE. EXPOSURE TO TEMPERATURES
ABOVE 120F MAY CAUSE CANS TO VENT, RUPTURE OR BURST.

Spill Release Procedures:REMOVE ALL SOURCES OF HEAT, SPARKS OR OPEN
FLAMES. VENTILATE THE AREA OF SPILL. ABSORB THE SPILL ON OIL
ABSORBENT, SAND OR VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER: POISON. MAY BE HARMFUL/FATAL
IF SWALLOWED. VAP HARMFUL. DIRECT CNTCT W/EYES OR SKIN WILL RSLT IN
IRRIT. AVOID USING PROD OUTDOORS ON A (ING 8)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES OR HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . DO NOT USE ON RUBBER, PLASTIC, LINOLEUM
OR A NY OTHER ORGANIC MATLS. TO (ING 15)

Respiratory Protection:VAP HARMFUL. AVOID BRTHG VAPS/SPRAY MIST OF
PROD. WEAR NIOSH APPRVD SCBA IF PROD MUST BE USED IN CONFINED AREA.
WEAR NIOSH APPRVD CARTRIDGE RESP IF TLV IS EXCEEDED OR WHEN
SPRAYING MORE THAN ONE-HALF CAN CONTINUOUSLY.
Ventilation:USE WITH ONLY ADEQUATE LOCAL MECHANICAL VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR LONG PANTS AND LONG SLEEVES.
Work Hygienic Practices:EYE PROTECTION & PROTECTIVE GLOVES ARE
RECOMMENDED ANY TIME YOU WORK W/ANY CONCENTRATED INDUSTRIAL
STRENGTH PRODUCTS.
Supplemental Safety and Health
FIRE FIGHT PROC: FROM VENTING, RUPTURING OR BURSTING CANS. MATL TO
AVOID: RUB, PLASTIC, LINOLEUM OR ANY ORG MATL. EXPLAN OF CARCIN:
1994:ANTIC TO BE CARCIN. EFTS OF OVEREXP: CONFUSION, DEPRESS,
FATIGU E, LOSS OF APPETITE, NAUS, VOMIT, COUGH, LOSS OF SENSE OF
BALANCE & VISUAL DISTURBS. ALSO COULD CAUSE LIVER DISEASE.

Boiling Pt:B.P. Text:>-40F,>-40C
Vapor Density:4.0
Spec Gravity:0.9 (H*2O=1)
Solubility in Water:NIL
Appearance and Odor:A CLEAR AEROSOL GEL WITH A STRONG SOLVENT ODOR.
Percent Volatiles by Volume:>90 WT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CAUSTICS OR CHEMICALLY ACTIVE LIGHT METALS. MAY
ADVERSELY AFFECT SOME PLASTICS. DO NOT USE ON (SUPDAT)
Stability Condition to Avoid:FLAMMABLE. DO NOT EXPOSE TO TEMPERATURES
ABOVE 120F, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING PROD MAY RSLT IN FORMATION OF
CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE OR TRACES OF
PHOSGENE GASES.

Waste Disposal Methods:DO NOT INCINERATE CANS. CONTENTS UNDER PRESSURE.
DISPOSE OF LIQUID AS AN EPA RCRA HAZARDOUS WASTE. FOLLOW ALL
FEDERAL, STATE AND LOCAL REGULATIONS REGARDING WASTE DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.